Chapter/Index: Introduction  A  B  C  D  E  F  G  H  I  J  K  L  M  N  O  P  Q  R  S  T  U  V  W  X  Y  Z  Appendix
In one dimensional (1D) FVdM (Frank and Van der Merwe) model in Figure 3492a, the atoms connected with the harmonic springs, representing a periodic potential, interact with each other with period b. The Hamiltonian may be taken to be,  [3492a] Figure 3492a. The 1D FVdM model. The springs represent interactions between atoms: where, In the case with a periodic potential V = 0, the harmonic term H would lead to a lattice constant a_{0}, which, in general, would be incommensurable with b as shown in Figure 3492a (b). In a diffraction experiment one would observe Bragg spots (or sheets) at positions Q = 2πN/a_{0} (N is an integer). If the potential V is strong enough the lattice may tend to relax into a comrnensurate (C) structure where the average lattice spacing a is a simple rational fraction of the period b as shown in Figure 3492a (a). Even in the case where the potential is not strong enough to force the chain into commensurability, the potential will still modulate the chain. That means, the atoms will move towards the potential minima. The average period may be close to a simple commensurate value, but still be incommensurate. In the most general incommensurate structure the position of the n^{th} atom may be given by, [1  2] x_{n} = na + α + f(na + α)  [3492b] where, However, chaotic structures cannot be described by Equation 3492b, where the diffraction pattern is not made up of welldefined Bragg spots.
[1] Janner A and Janssen T 1977 Phys. Rev. B 15 643.
