Practical Electron Microscopy and Database

An Online Book, Second Edition by Dr. Yougui Liao (2006)

Practical Electron Microscopy and Database - An Online Book

Chapter/Index: Introduction | A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | Appendix

Dependence of Emission Coefficient of Secondary Electrons on Atomic Number and Accelerating Voltage of Incident Beam

Unlike the situation for backscattered electrons, the fraction of secondary electrons (SEs) produced is relatively independent of the atomic number of the scattering atoms as shown in Figure 4803a. Table 4803 lists some examples of secondary electron (SE) coefficients of elements in periodic table, generated with incident electron irradiation at voltages from 2 keV to 100 keV.

Emission Coefficients of Backscattering Electrons (η) and Secondary Electrons (δ)

Figure 4803a. Schematic shows emission coefficients of backscattering electrons (η) and secondary electrons (δ), depending on atomic number (Z).

 

Table 4803. Examples of secondary electron (SE) coefficients of elements in periodic table (at 2 keV to 100 keV of incident electron irradiation).
No.
 
Atomic
Weight
Name Symbol 2 keV 5 keV 10 keV 20 keV 50 keV 100 keV Electron
configuration
Ionization
energy (eV)
1 1.0079 Hydrogen H             1s1 13.5984
2 4.0026 Helium He         1s2 24.5874
3 6.941 Lithium Li           [He] 2s1 5.3917
4 9.0122 Beryllium Be           [He] 2s2 9.3227
5 10.811 Boron B           [He] 2s2 2p1 8.298
6 12.0107 Carbon C             [He] 2s2 2p2 11.2603
7 14.0067 Nitrogen N           [He] 2s2 2p3 14.5341
8 15.9994 Oxygen O             [He] 2s2 2p4 13.6181
9 18.9984 Fluorine F             [He] 2s2 2p5 17.4228
10 20.1797 Neon Ne         [He] 2s2 2p6 21.5645
11 22.9897 Sodium Na             [Ne] 3s1 5.1391
12 24.305 Magnesium Mg             [Ne] 3s2 7.6462
13 26.9815 Aluminum Al   0.4   0.1 0.05   [Ne] 3s2 3p1 5.9858
14 28.0855 Silicon Si             [Ne] 3s2 3p2 8.1517
15 30.9738 Phosphorus P             [Ne] 3s2 3p3 10.4867
16 32.065 Sulfur S             [Ne] 3s2 3p4 10.36
17 35.453 Chlorine Cl             [Ne] 3s2 3p5 12.9676
18 39.948 Argon Ar         [Ne] 3s2 3p6 15.7596
19 39.0983 Potassium K             [Ar] 4s1 4.3407
20 40.078 Calcium Ca             [Ar] 4s2 6.1132
21 44.9559 Scandium Sc           [Ar] 3d1 4s2 6.5615
22 47.867 Titanium Ti             [Ar] 3d2 4s2 6.8281
23 50.9415 Vanadium V           [Ar] 3d3 4s2 6.7462
24 51.9961 Chromium Cr             [Ar] 3d5 4s1 6.7665
25 54.938 Manganese Mn             [Ar] 3d5 4s2 7.434
26 55.845 Iron Fe             [Ar] 3d6 4s2 7.9024
27 58.9332 Cobalt Co           [Ar] 3d7 4s2 7.881
28 58.6934 Nickel Ni             [Ar] 3d8 4s2 7.6398
29 63.546 Copper Cu           [Ar] 3d10 4s1 7.7264
30 65.39 Zinc Zn           [Ar] 3d10 4s2 9.3942
31 69.723 Gallium Ga           [Ar] 3d10 4s2 4p1 5.9993
32 72.64 Germanium Ge           [Ar] 3d10 4s2 4p2 7.8994
33 74.9216 Arsenic As           [Ar] 3d10 4s2 4p3 9.7886
34 78.96 Selenium Se           [Ar] 3d10 4s2 4p4 9.7524
35 79.904 Bromine Br           [Ar] 3d10 4s2 4p5 11.8138
36 83.8 Krypton Kr         [Ar] 3d10 4s2 4p6 13.9996
37 85.4678 Rubidium Rb           [Kr] 5s1 4.1771
38 87.62 Strontium Sr           [Kr] 5s2 5.6949
39 88.9059 Yttrium Y           [Kr] 4d1 5s2 6.2173
40 91.224 Zirconium Zr             [Kr] 4d2 5s2 6.6339
41 92.9064 Niobium Nb           [Kr] 4d4 5s1 6.7589
42 95.94 Molybdenum Mo           [Kr] 4d5 5s1 7.0924
43 * 98 Technetium Tc           [Kr] 4d5 5s2 7.28
44 101.07 Ruthenium Ru           [Kr] 4d7 5s1 7.3605
45 102.9055 Rhodium Rh           [Kr] 4d8 5s1 7.4589
46 106.42 Palladium Pd           [Kr] 4d10 8.3369
47 107.8682 Silver Ag           [Kr] 4d10 5s1 7.5762
48 112.411 Cadmium Cd           [Kr] 4d10 5s2 8.9938
49 114.818 Indium In           [Kr] 4d10 5s2 5p1 5.7864
50 118.71 Tin Sn           [Kr] 4d10 5s2 5p2 7.3439
51 121.76 Antimony Sb           [Kr] 4d10 5s2 5p3 8.6084
52 127.6 Tellurium Te           [Kr] 4d10 5s2 5p4 9.0096
53 126.9045 Iodine I           [Kr] 4d10 5s2 5p5 10.4513
54 131.293 Xenon Xe         [Kr] 4d10 5s2 5p6 12.1298
55 132.9055 Cesium Cs           [Xe] 6s1 3.8939
56 137.327 Barium Ba             [Xe] 6s2 5.2117
57 138.9055 Lanthanum La           [Xe] 5d1 6s2 5.5769
58 140.116 Cerium Ce           [Xe] 4f1 5d1 6s2 5.5387
59 140.9077 Praseodymium Pr           [Xe] 4f3 6s2 5.473
60 144.24 Neodymium Nd           [Xe] 4f4 6s2 5.525
61 * 145 Promethium Pm           [Xe] 4f5 6s2 5.582
62 150.36 Samarium Sm           [Xe] 4f6 6s2 5.6437
63 151.964 Europium Eu           [Xe] 4f7 6s2 5.6704
64 157.25 Gadolinium Gd           [Xe] 4f7 5d1 6s2 6.1501
65 158.9253 Terbium Tb           [Xe] 4f9 6s2 5.8638
66 162.5 Dysprosium Dy           [Xe] 4f10 6s2 5.9389
67 164.9303 Holmium Ho           [Xe] 4f11 6s2 6.0215
68 167.259 Erbium Er           [Xe] 4f12 6s2 6.1077
69 168.9342 Thulium Tm           [Xe] 4f13 6s2 6.1843
70 173.04 Ytterbium Yb           [Xe] 4f14 6s2 6.2542
71 174.967 Lutetium Lu           [Xe] 4f14 5d1 6s2 5.4259
72 178.49 Hafnium Hf           [Xe] 4f14 5d2 6s2 6.8251
73 180.9479 Tantalum Ta           [Xe] 4f14 5d3 6s2 7.5496
74 183.84 Tungsten W           [Xe] 4f14 5d4 6s2 7.864
75 186.207 Rhenium Re           [Xe] 4f14 5d5 6s2 7.8335
76 190.23 Osmium Os           [Xe] 4f14 5d6 6s2 8.4382
77 192.217 Iridium Ir           [Xe] 4f14 5d7 6s2 8.967
78 195.078 Platinum Pt           [Xe] 4f14 5d9 6s1 8.9587
79 196.9665 Gold Au   0.7   0.2 0.1   [Xe] 4f14 5d10 6s1 9.2255
80 200.59 Mercury Hg           [Xe] 4f14 5d10 6s2 10.4375
81 204.3833 Thallium Tl           [Xe] 4f14 5d10 6s2 6p1 6.1082
82 207.2 Lead Pb           [Xe] 4f14 5d10 6s2 6p2 7.4167
83 208.9804 Bismuth Bi           [Xe] 4f14 5d10 6s2 6p3 7.2856
84 * 209 Polonium Po           [Xe] 4f14 5d10 6s2 6p4 8.417
85 * 210 Astatine At         [Xe] 4f14 5d10 6s2 6p5 9.3
86 * 222 Radon Rn         [Xe] 4f14 5d10 6s2 6p6 10.7485
87 * 223 Francium Fr         [Rn] 7s1 4.0727
88 * 226 Radium Ra           [Rn] 7s2 5.2784
89 * 227 Actinium Ac           [Rn] 6d1 7s2 5.17
90 232.0381 Thorium Th           [Rn] 6d2 7s2 6.3067
91 231.0359 Protactinium Pa         [Rn] 5f2 6d1 7s2 5.89
92 238.0289 Uranium U           [Rn] 5f3 6d1 7s2 6.1941
93 * 237 Neptunium Np           [Rn] 5f4 6d1 7s2 6.2657
94 * 244 Plutonium Pu           [Rn] 5f6 7s2 6.0262
95 * 243 Americium Am           [Rn] 5f7 7s2 5.9738
96 * 247 Curium Cm         5.9915
97 * 247 Berkelium Bk         6.1979
98 * 251 Californium Cf         6.2817
99 * 252 Einsteinium Es       6.42
100 * 257 Fermium Fm       6.5
101 * 258 Mendelevium Md     6.58
102 * 259 Nobelium No       6.65
103 * 262 Lawrencium Lr       4.9
104 * 261 Rutherfordium Rf    
105 * 262 Dubnium Db    
106 * 266 Seaborgium Sg    
107 * 264 Bohrium Bh    
108 * 277 Hassium Hs    
109 * 268 Meitnerium Mt    
No.
 
Atomic
Weight
Name Symbol 2 keV 5 keV 10 keV 20 keV 50 keV 100 keV Electron
configuration
Ionization
energy (eV)

Figure 4803b shows the simulated and experimental yields of SEs for the electron incident voltages lower than 5 keV for a silicon sample.

Simulated and experimental yields of SEs for the electron incident voltages lower than 5 keV for a silicon sample

Figure 4803b. Simulated and experimental yields of SEs for the electron incident voltages lower than 5 keV for a silicon sample. [1, 2]

 

 

 

 

 

 

 

 

[1] Hendrix Demers, Nicolas Poirier-Demers, Alexandre Real Couture, Dany Joly, Marc Guilmain, Niels De Jonge And Dominique Drouin, Three-Dimensional Electron Microscopy Simulation with the CASINO Monte Carlo Software, CANNING 33, 135–146 (2011).
[2] Bronstein IM, Fraiman BS. 1969. Vtorichnaya elektronnaya emissiya. Moskva: Nauka.