HRTEM and Electron Diffraction of Crystals with Trigonal Symmetry
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The structure [1] shown in Figure 3470a is formed by a three-dimensional (3-D) Cr7S12 framework raising the strips of edge-sharing octahedra {CrX6} as a triple twinning {111} of NaCl-type and thus, resulting in a hexagonal symmetry sublattice. This 3-D framework forms two different types of tunnels with hexagonal and trigonal geometry. The columns with composition A3CrX3 located in the hexagonal tunnels and the columns with composition A3X located in the trigonal tunnels. There are one hexagonal tunnel and two trigonal tunnels in an unit cell. Both types of columns present hexagonal lattices with the same lattice parameters.

Idealized structure model of PbCr2S4 projected onto (0001)

Figure 3470a. (a) Ideal structure of PbCr2S4 projected onto (0001). Pb, Cr and S atoms are drawn as medium black, small black and big gray circles. (b) The triangular tunnels. Black spheres represent Pb atoms and the gray ones located in the center of the face sharing Pb-prisms are S atoms. (c) The hexagonal tunnels. The black spheres represent Pb atoms and the S atoms are located at the corners of the face-sharing octahedra which are centered by Cr atoms. [2]

Figure 3470b shows the SAED (selected-area electron diffraction) patterns of A1-pCr2X4-p crystals along the [0001] zone axis, revealing only the Bragg reflections hk0, which are common to the three sublattices.

SAED pattern of PbCr2S4 crystals oriented along the [0001] zone axis

Figure 3470b. SAED pattern of PbCr2S4 crystals oriented along the [0001] zone axis. [2]

Surprisingly, the high-resolution images along [0001] (given in Figure 3470c) does not correspond to the expected six-fold symmetry as indicated in Figure 3470b, but to three-fold symmetry.

HRTEM image of a crystal of a PbCr2S4 crystal imaged along the [0001] zone axis

Figure 3470c. HRTEM image of a crystal of a PbCr2S4 crystal imaged along the [0001] zone axis. The unit cell is outlined. [2]

 

 

 

 

 

 

 

[1] Hyde, B.G., Andersson, S., 1989. Inorganic Crystal Structures. Wiley, New York.
[2] Landa-Cánovas, A.R., Gómez-Herrero, A., and Carlos Otero-Díaz, L. Electron microscopy study of incommensurate modulated structures in misfit ternary chalcogenides, Micron 32 (2001) 481 - 495.

 

 

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