Electron microscopy
 
EDS Measurement of Carbon
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The background counts in TEM-EDS are much lower than those in SEM-EDS spectrum. Due to the high background counts in SEM-EDS, an artificial carbon (C) peak is always visible and thus a value of more than 2% carbon is normally measured even though there is no carbon in the specimen. This artefact is due to the window in the detector. The EDS windows are normally SATW windows and their material has a specific transmission profile with a strong absorption edge just above but very close to the C X-ray energy, resulting in an artificial peak at the C energy position. Therefore, it is the strong absorption of the background (continuum) X-rays that produces the artefact peak. Note that SATW detector windows are AP* ultrathin polymer windows manufactured by Moxtek and are almost supplied by all EDS detector companies. However, a TEM-EDS spectrum taken from the same specimen materials does not show such a artefact peak at the carbon energy because the spectrum consists mostly of characteristic X-rays.

Figure 1853 shows the deconvolution of an EDX spectrum with peak overlaps, taken from a material that contains O, Ti, N, and C elements.

Deconvolution of an EDX spectrum with peak overlaps

Figure 1853. Deconvolution of an EDX spectrum with peak overlaps. [1]

[1] J. Berlin, T. Salge, M. Falke, and D. Goran, Recent Advances in EDS and EBSD Technology: Revolutionizing the Chemical Analysis of Chondritic Meteorites at the Micro- and Nanometer Scale, 42nd Lunar and Planetary Science Conference, 2723, (2011).

 

 

 

 

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