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Some compounds, such as VO₂, V₂O₃, V₆O₁₃, and several Magnéli phase (V_nO_2n-1) [1, 2], undergo metal-insulator transition (MIT) with a change of temperature.

[1] S.-Y. Li, G. A. Niklasson, and C. G. Granqvist, Thermochromism of VO2 Nanoparticles: Calculated Optical Properties and Applications to Energy Efficient Windows, MRS Proceedings 1315 (2011) mrsf10-1315-mm07-07
[2] S.-Y. Li, G.A. Niklasson, and C.G. Granqvist, Thermochromic fenestration with VO2-based materials: Three challenges and how they can be met, Thin Solid Films (2011), doi:10.1016/j.tsf.2011.10.053.