Practical Electron Microscopy and Database

An Online Book, Second Edition by Dr. Yougui Liao (2006)

Practical Electron Microscopy and Database - An Online Book

Chapter/Index: Introduction | A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | Appendix

TEM Imaging of Gadolinium Silicides

Table 981. TEM imaging of gadolinium silicides.

Gadolinium Silicides TEM images
GdSix Gd thin film deposited on (111)Si
Gd thin film deposited on (111)Si annealed at 150 °C. There is an amorphous interlayer (a-interlayer) and nucleation of the crystalline silicide. [1]
GdSi2-x
Gd/Si(111) samples annealed at 600 °C for 1 min. [1]
GdSi2-x HRTEM
Planar stacking faults, on {10-10} planes, along three <-12-10> and <0001> directions in epitaxial GdSi2-x thin films viewed along the [0001] direction. [2]
GdSi2-x
Coexistence of epitaxial H(hexagonal)-GdSi2-x and polycrystalline O(orthorhombic)-GdSi2 in a Gd/(001)Si sample annealed at 600 °C: (a) polycrystalline O-GdSi2 rings and two sets of epitaxial H-GdSi2-x (see page2036_f), with orientation relationships between H-GdSi2-x and (001)Si, which are (A) (1-100)GdSi2-x/(001)Si with [0001]GdSi2-x/[2-20]Si and (B) (1-100)GdSi2-x/(001)Si with [11-20]-GdSi2-x/[2-20]Si. The two sets of GdSi2-x are crystallographically equivalent with one rotating 90° relative to the other around the common [1-100]GdSi2-x axis. Two perpendicular orientations with the same Moire fringe spacings, indicating that the epitaxial films tend to orient with two different azimuthal orientations rotated by 90° with each other. [1]

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

[1] J.C. Chen, G.H. Shen, L.J. Chen, Interfacial reactions of Gd thin films on (111) and (001) Si, Applied Surface Science 142 (1999) 291–294.
[2] Lih J. Chen, Silicide Technology for Integrated Circuits, 2004.